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Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)

Aquachlorido(4-methylbenzoato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)

Authors :
Yan-Li Miao
Hao Wang
Wen-Dong Song
Source :
Acta Crystallographica Section E, Vol 64, Iss 5, Pp m716-m716 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

In the title mononuclear complex, [Cu(C8H7O2)Cl(C12H8N2)(H2O)], the CuII atom is coordinated by one carboxylate O atom from a monodentate 4-methylbenzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water molecule in a square-pyramidal geometry. The crystal structure exhibits inter- and intramolecular C—H...Cl, C—H...O, O—H...Cl and O—H...O hydrogen bonds, as well as C—H...π interactions of phenanthroline and methyl H atoms towards the π-systems of neighboring 4-methylbenzoate units and the pyridine rings of the phenanthroline system [centroid–centroid distances are 2.706 (2) and 2.992 (1) Å, respectively].

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
5
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.1082b4109d794073ac6bae6c216a0cc5
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536808010945