Back to Search Start Over

7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate

Authors :
Edward R. T. Tiekink
James L. Wardell
R. Alan Howie
Marcus V. N. de Souza
Marcelle de Lima Ferreira
Solange M. S. V. Wardell
Source :
Acta Crystallographica Section E, Vol 66, Iss 3, Pp o696-o697 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

The organic molecule in the title hydrate, C17H14ClN3O·H2O, has a small but significant twist from planarity, as seen in the dihedral angle of 12.10 (17)° between the quinoline and benzene rings. The conformation about the C=N bond is E. Chains along the b axis are formed in the crystal structure aided by water–quinoline O—H...N (× 2) and hydrazone–water N—H...O hydrogen bonds. Layers of these chains stack along the a axis via C—H...π and π–π interactions [ring centroid–ring centroid distance = 3.674 (2) Å]. C—H...O interactions are also present.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
3
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.0fbc8b7599f14a53bce0833e0073b9a0
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810006598