Surface-supported metal−organic frameworks with geometric topological diversity via scanning tunneling microscopy

Summary: Surface-supported metal−organic frameworks (SMOFs) are long-range ordered periodic 2D lattice layers formed by inorganic metal nodes and organic ligands via coordination bonds on substrate surfaces. The atomic resolution STM lays a solid foundation for the conception and construction of SMOFs with large area, stable structure, and special function. In this review, the cutting-edge research of SMOFs from design strategy, preparation process, and how to accurately achieve structural and functional diversity are reviewed. Furthermore, we focus on the design and construction of novel and fascinating periodic and fractal structures, in which some typical honeycomb structures, Kagome lattice, hexagonal geometry, and Sierpiński triangles are summarized, and the related prospects for designing functional nanoscale systems and architectures are prospected. Finally, the challenges faced in the design and synthesis of SMOFs are denoted, and the application prospect and development trend of SMOFs are forecasted based on the current research status.