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1,4-Diazabicyclo[2.2.2]octane-1,4-diium bis(3-chlorobenzoate)

Authors :
Zi-Shuo Yao
Osamu Sato
Source :
Acta Crystallographica Section E, Vol 70, Iss 2, Pp o154-o154 (2014)
Publication Year :
2014
Publisher :
International Union of Crystallography, 2014.

Abstract

In the title salt C6H14N22+·2C7H4ClO2−, two 3-chlorobenzoate (3CBA) anions are bridged by one diprotonated 1,4-diazabicyclo[2.2.2]octane-1,4-diium (H2DABCO2+) dication through N—H...O hydrogen bonds. In this way, a trimeric unit is generated, in which the mean planes of the two 3CBA anions are twisted with respect to each other by a dihedral angle of 59.87 (9)°. The trimeric units are linked into a three-dimensional network via weak C—H...O interactions.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
70
Issue :
2
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.0cd60df9a96543db9e79e17284c9133b
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536814000610