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Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate

Authors :
Ting Zhou
Yu-hua Long
Ding-qiao Yang
Han-mei Zhang
Wen-ling Wang
Source :
Acta Crystallographica Section E, Vol 66, Iss 8, Pp o2155-o2155 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

The title compound, C15H13Br4NO4, was obtained via radical bromination reaction of ethyl 6,7-dimethoxy-2-methylquinoline-3-carboxylate and N-bromosuccinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maximum deviation from the mean plane of 0.035 (1) Å. The dihedral angle between the six-membered rings is 2.33 (2)°. The methoxy O atoms of the two neighboring methoxy groups are in-plane while their methyl C atoms are located on either side of the quinolyl ring plane at distances of −1.207 (1) and 1.223 (1) Å.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.0a99c8aefd7469ea2806f8584162dd9
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810029351