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Evaluating the performance of oxidized Hg reference gas generators in the range ng m−3 to μg m−3 by improved coupling with ICP-MS

Authors :
Panayot Petrov
Timo Rajamäki
Warren T. Corns
Heidi Goenaga-Infante
Source :
Atmospheric Environment: X, Vol 8, Iss , Pp 100090- (2020)
Publication Year :
2020
Publisher :
Elsevier, 2020.

Abstract

We demonstrate a novel way to introduce a so-called Hg reference gas, produced by a gas generator, into an elemental detector, such as ICP-MS, and to directly measure gaseous oxidized mercury (GOM as HgCl2) at a wide range of concentrations, covering 4 orders of magnitude. The approach was tested using two types of generators based on the dilution of a gas saturated with mercury chloride vapours (from dry HgCl2 salt) and on the evaporation of aqueous HgCl2 standards. The former generator provided reference gas at μg m−3 concentrations, while the latter was applicable from low ng m−3 to μg m−3. The generation and measurement of gaseous Hg was achieved in real time without significant memory effects, and with a response time shorter than 5 min. This unique approach of direct measurement (without thermal conversion) of both gaseous elemental mercury (GEM) and GOM from environmentally relevant to industrial concentrations has been shown to offer the potential to significantly improve the reliability of Hg determination from gas generators. This, in the longer term, will be invaluable to improve accuracy of in-field Hg measurements.

Details

Language :
English
ISSN :
25901621
Volume :
8
Issue :
100090-
Database :
Directory of Open Access Journals
Journal :
Atmospheric Environment: X
Publication Type :
Academic Journal
Accession number :
edsdoj.0a66828205074b0281174cea178c87a6
Document Type :
article
Full Text :
https://doi.org/10.1016/j.aeaoa.2020.100090