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(1-Ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O)bis(triphenylphosphane)copper(I)

Authors :
Tobias Rüffer
Chris C. Joubert
Blenerhassit E. Buitendach
Jannie C. Swarts
Alexander Jakob
Heinrich Lang
Source :
Acta Crystallographica Section E, Vol 67, Iss 2, Pp m231-m232 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

In the title mononuclear coordination complex, [CuFe(C5H5)(C9H5F3O2)(C18H15P)2], the CuI ion is coordinated by the chelating β-diketonate 1-ferrocenyl-4,4,4-trifluorobutane-1,3-dione ligand through two O atoms and the two datively bonded triphenylphosphane ligands resulting in a distorted tetrahedral coordination sphere. The CuI ion, together with its chelating butane-1,3-dione group, is mutually coplanar [greatest displacement of an atom from this plane = 0.037 (1) Å], and the CuI ion lies slightly above [0.013 (1) Å] the plane. The overall geometry, including the bond distances and angles within the complex, corresponds to those of other reported copper(I) β-diketonates featuring organic groups at the β-diketonate ligand.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
2
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.09898c8b8de481ab2ce764799e0ee4f
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811001796