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(1-Ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O)bis(triphenylphosphane)copper(I)
- Source :
- Acta Crystallographica Section E, Vol 67, Iss 2, Pp m231-m232 (2011)
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography, 2011.
-
Abstract
- In the title mononuclear coordination complex, [CuFe(C5H5)(C9H5F3O2)(C18H15P)2], the CuI ion is coordinated by the chelating β-diketonate 1-ferrocenyl-4,4,4-trifluorobutane-1,3-dione ligand through two O atoms and the two datively bonded triphenylphosphane ligands resulting in a distorted tetrahedral coordination sphere. The CuI ion, together with its chelating butane-1,3-dione group, is mutually coplanar [greatest displacement of an atom from this plane = 0.037 (1) Å], and the CuI ion lies slightly above [0.013 (1) Å] the plane. The overall geometry, including the bond distances and angles within the complex, corresponds to those of other reported copper(I) β-diketonates featuring organic groups at the β-diketonate ligand.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 67
- Issue :
- 2
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.09898c8b8de481ab2ce764799e0ee4f
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536811001796