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Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2

Authors :
Nicole J. LiBretto
Yinan Xu
Aubrey Quigley
Ethan Edwards
Rhea Nargund
Juan Carlos Vega-Vila
Richard Caulkins
Arunima Saxena
Rajamani Gounder
Jeffrey Greeley
Guanghui Zhang
Jeffrey T. Miller
Source :
Nature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
Publication Year :
2021
Publisher :
Nature Portfolio, 2021.

Abstract

Silica-supported, single site, main group Zn(II) and Ga(III) ions catalyze ethylene and propylene oligomerization. Here, experimental and theoretical evidence suggests a Cossee-Arlman reaction mechanism similar to that for transition metal catalysts.

Subjects

Subjects :
Science

Details

Language :
English
ISSN :
20411723
Volume :
12
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Nature Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.0883a7441fb2463d8acac813c97935cd
Document Type :
article
Full Text :
https://doi.org/10.1038/s41467-021-22512-6