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Lanthanide Coordination Compounds with Monodentate Coordinated Β-diketone Heteroanalogue - (2,2,2-trichloro-n-(Dipiperidin-1-yl-phosphoryl)acetamide: Synthesis and Spectral Investigations

Authors :
Olena Litsis
Vladimir Ovchynnikov
Tatiana Sliva
Svitlana Shishkina
Vladimir Amirkhanov
Source :
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 13, Iss 1, Pp 15-23 (2018)
Publication Year :
2018
Publisher :
Academy of Sciences of Moldova, Institute of Chemistry, 2018.

Abstract

New mononuclear six-coordinate lanthanide coordination compounds [Ln (HL)3Cl3] (HL = (2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamideCCl3C(O)N(H)P(O)[N(CH2)5]2, carbacylamidophosphate (CAPh) type ligand) have been synthesized from non-aqueous solutions. The complexes have been characterized by elemental analysis, spectroscopic methods (FTIR, 1H- and 31P-NMR, UV-Vis). The structure of [Sm(HL)3Cl3] has been further confirmed by single crystal X-ray diffraction analysis.

Details

Language :
English
ISSN :
18571727 and 23451688
Volume :
13
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Publication Type :
Academic Journal
Accession number :
edsdoj.064a956fbd744c51a6356927b3724e7c
Document Type :
article
Full Text :
https://doi.org/10.19261/cjm.2017.466