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Lanthanide Coordination Compounds with Monodentate Coordinated Β-diketone Heteroanalogue - (2,2,2-trichloro-n-(Dipiperidin-1-yl-phosphoryl)acetamide: Synthesis and Spectral Investigations
- Source :
- Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 13, Iss 1, Pp 15-23 (2018)
- Publication Year :
- 2018
- Publisher :
- Academy of Sciences of Moldova, Institute of Chemistry, 2018.
-
Abstract
- New mononuclear six-coordinate lanthanide coordination compounds [Ln (HL)3Cl3] (HL = (2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamideCCl3C(O)N(H)P(O)[N(CH2)5]2, carbacylamidophosphate (CAPh) type ligand) have been synthesized from non-aqueous solutions. The complexes have been characterized by elemental analysis, spectroscopic methods (FTIR, 1H- and 31P-NMR, UV-Vis). The structure of [Sm(HL)3Cl3] has been further confirmed by single crystal X-ray diffraction analysis.
Details
- Language :
- English
- ISSN :
- 18571727 and 23451688
- Volume :
- 13
- Issue :
- 1
- Database :
- Directory of Open Access Journals
- Journal :
- Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.064a956fbd744c51a6356927b3724e7c
- Document Type :
- article
- Full Text :
- https://doi.org/10.19261/cjm.2017.466