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Triphenyltellurium chloride

Authors :
Ambika Chopra
Shalini Jain
Sanjay K. Srivastava
Sushil K. Gupta
Ray J. Butcher
Source :
Acta Crystallographica Section E, Vol 70, Iss 4, Pp o421-o422 (2014)
Publication Year :
2014
Publisher :
International Union of Crystallography, 2014.

Abstract

The asymmetric unit of the title compound, C18H15ClTe, contains two molecules which are in inverted orientations. The compound displays a tetrahedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically active. The dihedral angles between the three phenyl rings are 76.51 (16)/73.75 (16)/71.06 (17) and 78.60 (17)/77.67 (16)/79.11 (16)° in the two molecules. The crystal packing features eight C—H...π interactions.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
70
Issue :
4
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.039cbc88cb0d4ae58deed8dd2cbdd3c9
Document Type :
article
Full Text :
https://doi.org/10.1107/S160053681400498X