Back to Search Start Over

Momentum tunnelling between nanoscale liquid flows

Authors :
Coquinot, Baptiste
Bui, Anna T.
Toquer, Damien
Michaelides, Angelos
Kavokine, Nikita
Cox, Stephen J.
Bocquet, Lydéric
Source :
Nature Nanotechnology (2025)
Publication Year :
2025

Abstract

The world of nanoscales in fluidics is the frontier where the continuum of fluid mechanics meets the atomic, and even quantum, nature of matter. While water dynamics remains largely classical under extreme confinement, several experiments have recently reported coupling between water transport and the electronic degrees of freedom of the confining materials. This avenue prompts us to reconsider nanoscale hydrodynamic flows under the perspective of interacting excitations, akin to condensed matter frameworks. Here we show, using a combination of many-body theory and molecular simulations, that the flow of a liquid can induce the flow of another liquid behind a separating wall, at odds with the prediction of continuum hydrodynamics. We further show that the range of this 'flow tunnelling' can be tuned through the solid's electronic excitations, with a maximum occurring when these are at resonance with the liquid's charge density fluctuations. Flow tunnelling is expected to play a role in global transport across nanoscale fluidic networks, such as lamellar graphene oxide or MXene membranes. It further suggests exploiting the electronic properties of the confining walls for manipulating liquids via their dielectric spectra, beyond the nature and characteristics of individual molecules.

Details

Database :
arXiv
Journal :
Nature Nanotechnology (2025)
Publication Type :
Report
Accession number :
edsarx.2501.01253
Document Type :
Working Paper
Full Text :
https://doi.org/10.1038/s41565-024-01842-8