Doping-Induced Charge Density Wave and Ferromagnetism in the Van der Waals Semiconductor CrSBr

In materials with one-dimensional electronic bands, electron-electron interactions can produce intriguing quantum phenomena, including spin-charge separation and charge density waves (CDW). Most of these systems, however, are non-magnetic, motivating a search for anisotropic materials where the coupling of charge and spin may affect emergent quantum states. Here, electron doping the van der Waals magnetic semiconductor CrSBr induces an electronically driven quasi-1D CDW, which survives above room temperature. Lithium intercalation also increases the magnetic ordering temperature to 200 K and changes its interlayer magnetic coupling from antiferromagnetic to ferromagnetic. The spin-polarized nature of the anisotropic bands that give rise to this CDW enforces an intrinsic coupling of charge and spin. The coexistence and interplay of ferromagnetism and charge modulation in this exfoliatable material provides a promising platform for studying tunable quantum phenomena across a range of temperatures and thicknesses.
Comment: Main text: 30 pages, 4 figures, 1 table. Supplementary Information: 21 pages, 11 figures, 2 tables