Recycling failed photoelectrons via tertiary photoemission

A key insight of Einstein's theory of the photoelectric effect is that a minimum energy is required for photoexcited electrons to escape from a material. For the past century it has been assumed that photoexcited electrons of lower energies make no contribution to the photoemission spectrum. Here we demonstrate the conceptual possibility that the energy of these 'failed' photoelectrons-primary or secondary-can be partially recycled to generate new 'tertiary' electrons of energy sufficient to escape. Such a 'recycling' step goes beyond the traditional three steps of the photoemission process (excitation, transport, and escape), and, as we illustrate, it can be realized through a novel Auger mechanism that involves three distinct minority electronic states in the material. We develop a phenomenological three-band model to treat this mechanism within a revised four-step framework for photoemission, which contains robust features of linewidth narrowing and population inversion under strong excitation, reminiscent of the lasing phenomena. We show that the conditions for this recycling mechanism are likely satisfied in many quantum materials with multiple flat bands properly located away from the Fermi level, and elaborate on the representative case of SrTiO3 among other promising candidates. We further discuss how this mechanism can explain the recent observation of anomalous intense coherent photoemission from a SrTiO3 surface, and predict its manifestations in related experiments, including the 'forbidden' case of photoemission with photon energies lower than the work function. Our study calls for paradigm shifts across a range of fundamental and applied research fields, especially in the areas of photoemission, photocathodes, and flat-band materials.
Comment: 45 Pages, 14 Figures