Tracking topological defect motion and incommensurate charge order melting in a perovskite manganite

Charge order pervades the phase diagrams of many quantum materials where it competes with superconducting and magnetic phases, hosts electronic phase transitions and topological defects, and couples to the lattice generating intricate structural distortions. Incommensurate charge order is readily stabilized in manganese oxides where it is associated with anomalous electronic and magnetic properties, but its nanoscale structural inhomogeneity complicates precise characterization and understanding of these phases. Leveraging atomic-resolution variable temperature cryogenic scanning transmission electron microscopy (cryo-STEM), we characterize the thermal evolution of charge order in a model manganite system, finding that mobile networks of topological defects generate phase inhomogeneity and induce incommensuration in an otherwise lattice-locked modulation. The melting of charge order at high temperatures is accompanied by generation of additional defects which decouple large areas of the order from the lattice.
Comment: 14 pages, 6 figures