Band Gap Renormalization at Different Symmetry Points in Perovskites

Using ultrafast broad-band transient absorption (TA) spectroscopy of photo-excited MAPbBr3 thin films with probe continua in the visible and the mid-to-deep-UV ranges, we capture the ultrafast gap renormalization at the fundamental gap situated at the R symmetry point of the Brillouin Zone (BZ) and a higher energy gap at the M point. Global Lifetime analysis, Lifetime density distribution and spectral trace fitting analysis are applied to extract quantitative information. Our work confirms the similarity of the energy gap renormalization at both symmetry points, which rises within the instrument response function (IRF, ~250 fs) and decays in ~400-600 fs times, and an energy red-shift of ~90-150 meV. The ability to monitor different high symmetry points in photoexcited perovskites opens exciting prospects into the characterization of materials, which can be extended to a larger class of materials.
Comment: 16 pages, 4 figures