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High-pressure crystal growth and investigation of the metal-to-metal transition of Ruddlesden-Popper trilayer nickelates La$_4$Ni$_3$O$_{10}$
- Source :
- Journal of Crystal Growth 627, 127511 (2024)
- Publication Year :
- 2023
-
Abstract
- Single crystals of Ruddlesden-Popper nickelates La$_4$Ni$_3$O$_{10}$ were grown by means of the floating-zone technique at oxygen pressure of 20~bar. Our results reveal the effects of the annealing process under pressure on the crystal structure. We present the requirements for crystal growth and show how a reported ferromagnetic impurity phase can be avoided. The different growth and post-annealing processes result in two distinct phases $P2_1/a$ and {\it Bmab} in which the metal-to-metal transitions occur at 152~K and 136~K, respectively.
Details
- Database :
- arXiv
- Journal :
- Journal of Crystal Growth 627, 127511 (2024)
- Publication Type :
- Report
- Accession number :
- edsarx.2311.10673
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1016/j.jcrysgro.2023.127511