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Photochemical Upcycling of Ultrastrong Polyethylene Nanomembranes into Fibrous Carbon at Ambient Conditions
- Publication Year :
- 2023
-
Abstract
- The escalating global issue of plastic waste accumulation, specifically polyolefins, necessitates an urgent solution for upcycling these materials into beneficial compounds. Yet, achieving such upcycling without introducing carbon dioxide into the environment remains a formidable challenge. In this study, we demonstrate an eco-friendly approach for the photochemical conversion of ultrastrong, ultratransparent, and ultrathin polyethylene membrane into fibrous carbon nanomembrane at ambient conditions. The membrane was sputter-coated with platinum and cuprous oxide nanoparticles and exposed to simulated sunlight, resulting in a porous carbon membrane decorated with Pt nanoparticles. The new carbonized nanomembrane maintained the pristine membrane's morphology. The membrane exhibited high activity (2.11 mA/cm2) for electrochemical ethanol oxidation with stability over 1000 cycles. This work holds significance for sustainable plastic waste management and the design of new polyolefin materials in a circular economy.
- Subjects :
- Physics - Applied Physics
Condensed Matter - Materials Science
Subjects
Details
- Database :
- arXiv
- Publication Type :
- Report
- Accession number :
- edsarx.2311.07023
- Document Type :
- Working Paper