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The optical absorption in indirect semiconductor to semimetal PtSe2 arises from direct transitions

Authors :
Tharrault, Marin
Ayari, Sabrine
Arfaoui, Mehdi
Desgué, Eva
Goff, Romaric Le
Morfin, Pascal
Palomo, José
Rosticher, Michael
Jaziri, Sihem
Plaçais, Bernard
Legagneux, Pierre
Carosella, Francesca
Voisin, Christophe
Ferreira, Robson
Baudin, Emmanuel
Publication Year :
2023

Abstract

$\rm{PtSe_2}$ is a van der Waals material transitioning from an indirect bandgap semiconductor to a semimetal with increasing thickness. Its absorption threshold has been conjectured to originate from interband indirect transitions. By quantitative comparison between broadband ($0.8 - 3.0\,\rm{eV}$) optical absorption of high-quality exfoliated crystals and DFT ab-initio simulations, we prove instead that the optical absorption arises only from direct transitions. This understanding allows us to shed light on the semiconductor to semimetal transition and to explore the effect of stacking and excitons on the optical absorption.

Details

Database :
arXiv
Publication Type :
Report
Accession number :
edsarx.2311.01847
Document Type :
Working Paper