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Evaluation of insulating behavior by Pb Substitution and Pressure-Induced Superconductivity in La2O2Bi3-xPb1+xS6
- Publication Year :
- 2023
-
Abstract
- We report synthesis, characterization, and physical properties of layered bismuth-sulfide compounds La2O2Bi3-xPb1+xS6. We synthesized a new La2O2Bi3PbS6 compound, whose crystal structure is similar to those of the La2O2Bi3AgS6 superconductor or La2O2Bi2Pb2S6 (insulator) with a four-layer-type conducting layer. The crystal structure of La2O2Bi3PbS6 is characterized in a tetragonal P4/nmm space group, and the lattice parameters are a = 4.084(1) {\AA} and c = 19.71(2) {\AA}. The obtained La2O2Bi3PbS6 sample exhibits narrow gap semiconductor (metallic-like) transport behavior with an anomaly near the 160 K. A metallic-like to insulator transition has been observed through Pb substitution, with increasing x in La2O2Bi3-xPb1+xS6. Furthermore, we applied external pressure for x = 0 and observed pressure-induced superconductivity. The onset of superconductivity appeared at 0.93 GPa, and the highest transition temperature was 3.1 K at 2.21 GPa.<br />Comment: 10 pages, 8 figures, accepted in Superconductor Science and Technology
- Subjects :
- Condensed Matter - Superconductivity
Subjects
Details
- Database :
- arXiv
- Publication Type :
- Report
- Accession number :
- edsarx.2308.05300
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1088/1361-6668/aceeba