Bringing ultimate depth to scanning tunnelling microscopy: deep subsurface vision of buried nano-objects in metals

A method for subsurface visualization and characterization of hidden subsurface nano-structures based on Scanning Tuneling Microscopy/Spectroscopy (STM/STS) has been developed. The nano-objects buried under a metal surface up to several tens of nanometers can be visualized through the metal surface and characterized with STM without destroying the sample. This non-destructive method exploits quantum well (QW) states formed by partial electron confinement between the surface and buried nano-objects. The specificity of STM allows for nano-objects to be singled out and easily accessed. Then, their shape, size and burial depth can be determined by analyzing the spatial distribution and oscillatory behavior of the electron density at the surface of the sample. The proof of concept was demonstrated by fabricating argon nanoclusters embedded into a single-crystalline Cu matrix. Taking advantage of the specific electronic band structure Cu and inner electron focusing, we experimentally demonstrated that noble-gas nanoclusters of several nanometers large buried as deep as 80 nm can be detected, characterized and imaged. The ultime depth of this ability is estimated as 110 nm. This approach using QW states paves the way for an enhanced 3D characterization of nanostructures hidden well below a metallic surface.
Comment: Accepted in Nanoscale Horizons Nanoscale Horiz., 2023, Accepted Manuscript https://doi-org.bases-doc.univ-lorraine.fr/10.1039/D3NH00052D