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Helium-bearing superconductor at high pressure
- Publication Year :
- 2022
-
Abstract
- Helium (He) is the most inert noble gas at ambient conditions. It adopts a hexagonal close packed structure (P63/mmc) and remains in the insulating phase up to 32 TPa. In contrast, lithium (Li) is one of the most reactive metals at zero pressure, while its cubic high-pressure phase (Fd-3m) is a weak metallic electride above 475 GPa. Strikingly, a stable compound of Li5He2 (R-3m) was formed by mixing Fd-3m Li with P63/mmc He above 700 GPa. The presence of helium promotes the lattice transformation from Fd-3m Li to Pm-3m Li, and tuns the three-dimensional distributed interstitial electrons into the mixture of zero- and two-dimensional anionic electrons. This significantly increases the degree of metallization at the Fermi level, consequently, the coupling of conductive anionic electrons with the Li-dominated vibrations is the key factor to the formation of superconducting electride Li5He2 with a transition temperature up to 26 K, dynamically stable to pressures down to 210 GPa.<br />Comment: 5 pages, 3 figures
- Subjects :
- Condensed Matter - Superconductivity
Physics - Computational Physics
Subjects
Details
- Database :
- arXiv
- Publication Type :
- Report
- Accession number :
- edsarx.2209.15241
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1103/PhysRevB.106.L220501