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Pressure-driven relaxation processes in nanocomposite ionic glass LiFe$_{0.75}$V$_{0.10}$PO$_{4}$

Authors :
Starzonek, Szymon
Rzoska, Sylwester J.
Drozd-Rzoska, Aleksandra
Bockowski, Michal
Pietrzak, Tomasz K.
Garbarczyk, Jerzy E.
Publication Year :
2022

Abstract

This paper presents results for systems formed in a solid glassy state after nanocrystallization process above the glass temperature. We analyze electric conductivity and relaxation processes after such treatment under high temperature (HT) and high pressure (HP-HT) as well. The latter leads to ca. 8% increase of density, two decades (100) increase of electric conductivity as well as qualitative changes in relaxation processes. The previtreous-type changes of the relaxation time on cooling is analyzed by the use of critical-like and the 'critical-activated' description. Presented results correspond well with obtained for this material and shown in ref. [8]. The evidence for pressure evolution of the glass and crystallization temperatures, indicating the unique possibility of maxima and crossovers is also reported.

Details

Database :
arXiv
Publication Type :
Report
Accession number :
edsarx.2206.13300
Document Type :
Working Paper
Full Text :
https://doi.org/10.1016/j.jnoncrysol.2023.122163