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Diffusion coefficient power laws and defect-driven glassy dynamics in swap acceleration

Authors :
Gopinath, Gautham
Lee, Chun-Shing
Gao, Xin-Yuan
An, Xiao-Dong
Chan, Chor-Hoi
Yip, Cho-Tung
Deng, Hai-Yao
Lam, Chi-Hang
Source :
Phys. Rev. Lett. 129, 168002 (2022)
Publication Year :
2021

Abstract

Particle swaps can drastically accelerate dynamics in glass. The mechanism is expected to be vital for a fundamental understanding of glassy dynamics. To extract defining features, we propose a partial swappability with a fraction {\phi_s} of swap-initiating particles, which can only swap locally with each other or with regular particles. We focus on the swap-dominating regime. At all temperatures studied, particle diffusion coefficients scale with {\phi_s} in unexpected power laws with temperature-dependent exponents, consistent with the kinetic picture of glass transition. At small {\phi_s}, swap-initiators, becoming defect particles, induce remarkably typical glassy dynamics of regular particles. This supports defect models of glass.<br />Comment: 14 pages, 20 figures

Details

Database :
arXiv
Journal :
Phys. Rev. Lett. 129, 168002 (2022)
Publication Type :
Report
Accession number :
edsarx.2111.11697
Document Type :
Working Paper
Full Text :
https://doi.org/10.1103/PhysRevLett.129.168002