Revealing the Intrinsic Magnetism of Non-Magnetic Glasses

Ordinary multi-component silicate glasses belong to a class of amorphous insulators normally displaying no special form of magnetism, save for the Larmor dominant diamagnetism from the constituent atoms' core electrons and the extrinsic Langevin paramagnetism due to the ubiquitous Fe-group dilute paramagnetic impurities. Here we show that the macroscopic magnetisation of three case-study glass types measured in a SQUID-magnetometer cannot be explained solely by means of the Larmor-Langevin contributions. In particular, we reveal a novel {\em intrinsic} contribution to the bulk magnetisation due to the amorphous structure itself, a contribution that is peculiar both in its temperature and magnetic-field dependence and represents the first true magnetic effect in nominally non-magnetic glasses. The only theoretical interpretation we know of for such an effect and which can consistently explain the experimental data demands the re-thinking of the atomic organisation of glasses at the nanometric scale.
Comment: Submitted for publication