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Twisted loxodromes in spindle-shaped polymer nematics

Authors :
Ansell, Helen S.
Kamien, Randall D.
Source :
Soft Matter 17 (2021) 7076
Publication Year :
2021

Abstract

We develop an energetic model that captures the twisting behavior of spindle-shaped polymer microparticles with nematic ordering, which display remarkably different twisting behavior to ordinary nematics confined to spindles. We have previously developed a geometric model of the twisting, based on experimental observations, in which we showed that the twist pattern follows loxodrome spirals [Ansell et. al., Phys. Rev. Lett., 123, 157801 (2019)]. In this study, we first consider a spindle-shaped surface and show that the loxodrome twisting behavior of our system can be captured by the Frank free energy of the nematic with an additional term constraining the length of the integral curves of the system. We then extend the ideas of this model to the bulk and explore the parameter space for which the twisted loxodrome solution is energetically favorable.<br />Comment: 10 pages, 7 figures

Details

Database :
arXiv
Journal :
Soft Matter 17 (2021) 7076
Publication Type :
Report
Accession number :
edsarx.2105.11526
Document Type :
Working Paper
Full Text :
https://doi.org/10.1039/D1SM00772F