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Richardson-Gaudin geminal wavefunctions in a Slater determinant basis

Authors :
Fecteau, Charles-Émile
Berthiaume, Frédéric
Khalfoun, Meriem
Johnson, Paul Andrew
Publication Year :
2020

Abstract

Geminal wavefunctions have been employed to model strongly-correlated electrons. These wavefunctions represent products of weakly-correlated pairs of electrons and reasonable approximations are computable with polynomial cost. In particular, Richardson-Gaudin states have recently been employed as a variational ansatz. This contribution serves to explain the Richardson-Gaudin wavefunctions in the conventional language of quantum chemistry.

Subjects

Subjects :
Physics - Chemical Physics

Details

Database :
arXiv
Publication Type :
Report
Accession number :
edsarx.2009.08349
Document Type :
Working Paper