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Cycle completion times probe interactions with environment
- Source :
- J. Phys. Chem. Lett. 2020, 11, 16, 6887-6891 (2020)
- Publication Year :
- 2020
-
Abstract
- Recent measurements of durations of non-equilibrium processes provide valuable information on microscopic mechanisms and energetics. Comprehensive theory for corresponding experiments so far is well developed for single-particle systems only. Little is known for interacting systems in non-equilibrium environments. Here, we introduce and study a basic model for cycle processes interacting with an environment that can exhibit a net particle flow. We find a surprising richness of cycle time variations with environmental conditions. This manifests itself in unequal cycle times $\tau^+$ and $\tau^-$ in forward and backward cycle direction with both asymmetries $\tau^-<\tau^+$ and $\tau^->\tau^+$, speeding up of backward cycles by interactions, and dynamical phase transitions, where cycle times become multimodal functions of the bias. The model allows us to relate these effects to specific microscopic mechanisms, which can be helpful for interpreting experiments.<br />Comment: 13 pages, 4 figures
- Subjects :
- Condensed Matter - Statistical Mechanics
Condensed Matter - Soft Condensed Matter
Subjects
Details
- Database :
- arXiv
- Journal :
- J. Phys. Chem. Lett. 2020, 11, 16, 6887-6891 (2020)
- Publication Type :
- Report
- Accession number :
- edsarx.2006.11247
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1021/acs.jpclett.0c01998