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Pure Molecular Beam of Water Dimer

Authors :
Bieker, Helen
Onvlee, Jolijn
Johny, Melby
He, Lanhai
Kierspel, Thomas
Trippel, Sebastian
Horke, Daniel A.
Küpper, Jochen
Publication Year :
2019

Abstract

Spatial separation of water dimer from water monomer and larger water-clusters through the electric deflector is presented. A beam of water dimer with $93~\%$ purity and a rotational temperature of $1.5~$K was obtained. Following strong-field ionization using a $35~$fs laser pulse with a wavelength centered around $800~$nm and a peak intensity of $10^{14}~\text{W}/\text{cm}^2$ we observed proton transfer and $46~\%$ of the ionized water dimer broke apart into a hydronium ion $\text{H}_3\text{O}^+$ and neutral OH.

Details

Database :
arXiv
Publication Type :
Report
Accession number :
edsarx.1904.08716
Document Type :
Working Paper
Full Text :
https://doi.org/10.1021/acs.jpca.9b06460