The suppressed radiative recombination rate in a quantum photocell with three electron donors

The radiative recombination of electron-hole pairs represents a great challenge to the photon-to-charge efficiency in the photocell. In this paper, we investigate how to suppress radiative recombination rate (RRR) in a proposed quantum photocell with three dipole-dipole coupled and uncoupled electron donors. The results showed that the RRR could be suppressed in this photocell with three uncoupled electron donors but be enhanced with three dipole-dipole coupled electron donors by the ambient circumstance temperatures, and the increasing energy gap in the donors, the decreasing gap between the donors and acceptor inhabited the RRR with three dipole-dipole both coupled and uncoupled electron donors. When the photocell was manipulated by the electrostatic dipole-dipole coupling strength J at room temperature, the RRR was suppressed to a smaller minimum by the gap between the donors and acceptor than those by different gaps in the donors. These suppressed strategies for RRR point out some significant ways to increase the photon-to-charge efficiency and deserve the further experimental verification.
Comment: 10 pages, 8 figures