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Nonadiabatic QED correction to the dissociation energy of the hydrogen molecule

Authors :
Puchalski, M.
Czachorowski, J. Komasa. P.
Pachucki, K.
Source :
Phys. Rev. Lett. 122, 103003 (2019)
Publication Year :
2018

Abstract

The quantum electrodynamic correction to the energy of the hydrogen molecule has been evaluated without expansion in the electron-proton mass ratio. The obtained results significantly improve the accuracy of theoretical predictions reaching the level of 1 MHz for the dissociation energy, in a very good agreement with the parallel measurement [H\"olsch et al., Phys. Rev. Lett. 122, 103002 (2019)]. Molecular hydrogen has thus become a cornerstone of ultraprecise quantum chemistry, which opens perspectives for determination of fundamental physical constants from its spectra.<br />Comment: 5 pages

Subjects

Subjects :
Physics - Atomic Physics

Details

Database :
arXiv
Journal :
Phys. Rev. Lett. 122, 103003 (2019)
Publication Type :
Report
Accession number :
edsarx.1812.02980
Document Type :
Working Paper
Full Text :
https://doi.org/10.1103/PhysRevLett.122.103003