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Site selective spin and orbital excitations in Fe3O4

Authors :
Elnaggar, H.
Wang, R.
Lafuerza, S.
Paris, E.
Komarek, A. C.
Guo, H.
Tseng, Y.
McNally, D.
Frati, F.
Haverkort, M. W.
Sikora, M.
Schmitt, T.
de Groot, F. M. F.
Publication Year :
2018

Abstract

$Fe_3O_4$ is a mixed-valence strongly correlated transition metal oxide which displays the intriguing metal to insulator Verwey transition. Here we investigate the electronic and magnetic structure of $Fe_3O_4$ by a unique combination of high-resolution Fe 2p3d resonant inelastic scattering magnetic circular (RIXS-MCD) and magnetic linear (RIXS-MLD) dichroism. We show that by coupling the site selectivity of RIXS with the magnetic selectivity imposed by the incident polarization handedness, we can unambiguously identify spin-flip excitations and quantify the exchange interaction of the different sublattices. Furthermore, our RIXS-MLD measurements show spin-orbital excitations that exhibit strong polarization and magnetic field dependence. Guided by theoretical simulations, we reveal that the angular dependence arises from a strong interplay between trigonal crystal-field, magnetic exchange and spin-orbit interaction at the nominal $Fe^{2+}$ sites. Our results highlight the capabilities of RIXS magnetic dichroism studies to investigate the ground state of complex systems where in-equivalent sites and bonds are simultaneously present.

Details

Database :
arXiv
Publication Type :
Report
Accession number :
edsarx.1811.04836
Document Type :
Working Paper