A Liquid Scintillation Detector for Radioassay of Gadolinium-Loaded Liquid Scintillator for the LZ Outer Detector

We report on the design and performance of the LUX-ZEPLIN (LZ) "Screener", a small liquid scintillator detector consisting of $\approx 23$ kg of LAB-based gadolinium-loaded liquid scintillator (GdLS) to be used in the LZ Outer Detector. The Outer Detector will be filled with 17.3 tonnes of GdLS and will surround the central liquid xenon time projection chamber of LZ. Its primary function will be to veto neutron single-scatter events in the liquid xenon which could mimic a WIMP dark matter signal. To meet the requirements for the Outer Detector, the radioimpurity levels in the GdLS must be kept below $\lesssim0.07$ mBq/kg. This background level corresponds to a rate of $\approx50$ Hz above an energy threshold of 100 keV. The Screener was operated in the ultra-low-background environment of the former LUX water shield in the Davis Laboratory at the Sanford Underground Research Facility for radioassay of the GdLS. Careful selection of detector materials and use of ultra-low-background PMTs allows the measurement of a variety of radioimpurities. The $^{14}\textrm{C}$/$^{12}\textrm{C}$ ratio in the scintillator is measured to be $(2.83\pm0.06\textrm{(stat.)}\pm0.01\textrm{(sys.)}) \times 10^{-17}$. Use of pulse shape discrimination allows the concentration of isotopes throughout the $^{238}\textrm{U}$, $^{235}\textrm{U}$, and $^{232}\textrm{Th}$ chains to be measured by fitting the collected spectra from $\alpha$ and $\beta$ events. We find that equilibrium is broken in the $^{238}\textrm{U}$ and $^{232}\textrm{Th}$ chains and that a significant portion of the contamination in the GdLS results from decays in the $^{227}\textrm{Ac}$ subchain of the $^{235}\textrm{U}$ series. Predictions for the singles rate in the Outer Detector are presented. The rate from radioimpurities above 100 keV in the GdLS is estimated to be $97.9\pm6.4$ Hz, with $65.5\pm1.9$ Hz resulting from $\alpha$-decays.