Microstructure and properties of Cu-Sn-Zn-TiO2 Nano-composite coatings on mild steel

Cu-Sn-Zn coatings have been widely used in industry for their unique properties, such as good conductivity, high corrosion resistance and excellent solderability. To further improve the mechanical performance of Cu-Sn-Zn coatings, powder-enhanced method was applied in the current study and Cu-Sn-Zn-TiO2 nano-composite coatings with different TiO2 concentration were fabricated. The microstructure of Cu-Sn-Zn-TiO2 nano-composite coatings were investigated by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). The mechanical properties of coatings including microhardness and wear resistance were studied. The results indicate that the incorporation of TiO2 nanoparticle can significantly influence the properties of Cu-Sn-Zn coatings. The microhardness of Cu-Sn-Zn coating was increased to 383 HV from 330 HV with 1g/L TiO2 addition. Also, the corrosion resistance of coating was enhanced. The effects of TiO2 nanoparticle concentration on the microstructure, mechanical properties and corrosion resistance of Cu-Sn-Zn-TiO2 nano-composite coatings were discussed.