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Quantum Process Tomography by 2D Fluorescence Spectroscopy
- Source :
- J. Chem. Phys. 142, 212442 (2015)
- Publication Year :
- 2015
-
Abstract
- Reconstruction of the dynamics (quantum process tomography) of the single-exciton manifold in energy transfer systems is proposed here on the basis of two-dimensional fluorescence spectroscopy (2D-FS) with phase-modulation. The quantum-process-tomography protocol introduced here benefits from, e.g., the sensitivity enhancement ascribed to 2D-FS. Although the isotropically averaged spectroscopic signals depend on the quantum yield parameter $\Gamma$ of the doubly-excited-exciton manifold, it is shown that the reconstruction of the dynamics is insensitive to this parameter. Applications to foundational and applied problems, as well as further extensions, are discussed.<br />Comment: 11 pages, 3 figures
Details
- Database :
- arXiv
- Journal :
- J. Chem. Phys. 142, 212442 (2015)
- Publication Type :
- Report
- Accession number :
- edsarx.1502.02363
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1063/1.4919954