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Predicting multidimensional distributive properties of hyperbranched polymer resulting from AB2 polymerization with substitution, cyclization and shielding
- Publication Year :
- 2013
-
Abstract
- A deterministic mathematical model for the polymerization of hyperbranched molecules accounting for substitution, cyclization, and shielding effect has been developed as a system of nonlinear population balances. The solution obtained by a novel approximation method shows perfect agreement with the analytical solution in limiting cases and provides, for the first time in this class of polymerization problems, full multidimensional results.<br />Comment: 38 pages, 22 figures
- Subjects :
- Mathematical Physics
Mathematics - Numerical Analysis
80A30, 82D60
Subjects
Details
- Database :
- arXiv
- Publication Type :
- Report
- Accession number :
- edsarx.1305.1034
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1016/j.polymer.2013.05.009