Persistent non-metallic behavior in Sr2IrO4 and Sr3Ir2O7 at high pressures

Authors :: Zocco, D. A.
Hamlin, J. J.
White, B. D.
Kim, B. J.
Jeffries, J. R.
Weir, S. T.
Vohra, Y. K.
Allen, J. W.
Maple, M. B.
Source :: J. Phys.: Condens. Matter 26, 255603 (2014)
Publication Year :: 2013
Abstract: Iridium-based 5d transition-metal oxides are attractive candidates for the study of correlated electronic states due to the interplay of enhanced crystal-field, Coulomb and spin-orbit interaction energies. At ambient pressure, these conditions promote a novel Jeff = 1/2 Mott insulating state, characterized by a gap of the order of ~0.1 eV. We present high-pressure electrical resistivity measurements of single crystals of Sr2IrO4 and Sr3Ir2O7. While no indications of a pressure-induced metallic state up to 55 GPa were found in Sr2IrO4, a strong decrease of the gap energy and of the resistance of Sr3Ir2O7 between ambient pressure and 104 GPa confirm that this compound is in the proximity of a metal-insulator transition.<br />Comment: 5 pages, 4 figures