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Why is the ground state electron configuration for Lithium $1s^22s$ ?
- Source :
- Europhysics Letters 100, 43002-1-4 (2012)
- Publication Year :
- 2012
-
Abstract
- The electronic ground state for Lithium is $1s^22s$, and not $1s^22p$. The traditional argument for why this is so is based on a screening argument that claims that the $2p$ electron is better shielded by the $1s$ electrons, and therefore higher in energy then the configuration that includes the $2s$ electron. We show that this argument is flawed, and in fact the actual reason for the ordering is because the electron-electron interaction energy is higher for the $2p-1s$ repulsion than it is for the $2s-1s$ repulsion.<br />Comment: 4 pages
- Subjects :
- Physics - Atomic Physics
Condensed Matter - Strongly Correlated Electrons
Subjects
Details
- Database :
- arXiv
- Journal :
- Europhysics Letters 100, 43002-1-4 (2012)
- Publication Type :
- Report
- Accession number :
- edsarx.1211.3240
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1209/0295-5075/100/43002