Back to Search Start Over

Why is the ground state electron configuration for Lithium $1s^22s$ ?

Authors :
Stacey, W. S.
Marsiglio, F.
Source :
Europhysics Letters 100, 43002-1-4 (2012)
Publication Year :
2012

Abstract

The electronic ground state for Lithium is $1s^22s$, and not $1s^22p$. The traditional argument for why this is so is based on a screening argument that claims that the $2p$ electron is better shielded by the $1s$ electrons, and therefore higher in energy then the configuration that includes the $2s$ electron. We show that this argument is flawed, and in fact the actual reason for the ordering is because the electron-electron interaction energy is higher for the $2p-1s$ repulsion than it is for the $2s-1s$ repulsion.<br />Comment: 4 pages

Details

Database :
arXiv
Journal :
Europhysics Letters 100, 43002-1-4 (2012)
Publication Type :
Report
Accession number :
edsarx.1211.3240
Document Type :
Working Paper
Full Text :
https://doi.org/10.1209/0295-5075/100/43002