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Efficient method for quantum calculations of molecule - molecule scattering properties in a magnetic field

Authors :
Suleimanov, Y. V.
Tscherbul, T. V.
Krems, R. V.
Source :
J. Chem. Phys. 137, 024103 (2012)
Publication Year :
2012

Abstract

We show that the cross sections for molecule - molecule collisions in the presence of an external field can be computed efficiently using a total angular momentum basis, defined either in the body-fixed frame or in the space-fixed coordinate system. This method allows for computations with much larger basis sets than previously possible. We present calculations for 15NH - 15NH collisions in a magnetic field. Our results support the conclusion of the previous study that the evaporative cooling of rotationally ground 15NH molecules in a magnetic trap has a prospect of success.

Details

Database :
arXiv
Journal :
J. Chem. Phys. 137, 024103 (2012)
Publication Type :
Report
Accession number :
edsarx.1202.0597
Document Type :
Working Paper
Full Text :
https://doi.org/10.1063/1.4733288