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Efficient method for quantum calculations of molecule - molecule scattering properties in a magnetic field
- Source :
- J. Chem. Phys. 137, 024103 (2012)
- Publication Year :
- 2012
-
Abstract
- We show that the cross sections for molecule - molecule collisions in the presence of an external field can be computed efficiently using a total angular momentum basis, defined either in the body-fixed frame or in the space-fixed coordinate system. This method allows for computations with much larger basis sets than previously possible. We present calculations for 15NH - 15NH collisions in a magnetic field. Our results support the conclusion of the previous study that the evaporative cooling of rotationally ground 15NH molecules in a magnetic trap has a prospect of success.
- Subjects :
- Physics - Atomic Physics
Physics - Chemical Physics
Subjects
Details
- Database :
- arXiv
- Journal :
- J. Chem. Phys. 137, 024103 (2012)
- Publication Type :
- Report
- Accession number :
- edsarx.1202.0597
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1063/1.4733288