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Nonequilibrium thermodynamics as a gauge theory

Authors :
Polettini, Matteo
Source :
EPL, 97 (2012) 30003
Publication Year :
2011

Abstract

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential. A widely accepted expression for the total entropy production of a system arises as the simplest gauge-invariant completion of the time derivative of Gibbs's entropy. We show that transition rates can be given a simple physical characterization in terms of locally-detailed-balanced heat reservoirs. It follows that Clausius's measure of irreversibility along a cyclic transformation is a geometric phase. In this picture, the gauge symmetry arises as the arbitrariness in the choice of a prior probability. Thermostatics depends on the information that is disposable to an observer; thermodynamics does not.<br />Comment: 6 pages. Non-fatal errors in eq.(6), eq.(26) and eq.(31) have been amended

Details

Database :
arXiv
Journal :
EPL, 97 (2012) 30003
Publication Type :
Report
Accession number :
edsarx.1110.0608
Document Type :
Working Paper
Full Text :
https://doi.org/10.1209/0295-5075/97/30003