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Reply to Comment on 'Failure of the work-Hamiltonian connection for free-energy calculations' by Horowitz and Jarzynski
- Publication Year :
- 2008
-
Abstract
- We show that the Comment [arXiv:0808.1224] by Horowitz and Jarzynski obtains as a main result a general free energy change for a harmonic system that in the macroscopic limit does not recover the textbook expression for the energy change of a Hookean spring. The reason is that Horowitz and Jarzynski improperly identify work with parametric changes of the Hamiltonian instead of with the standard quantity, force times displacement.<br />Comment: To appear in Physical Review Letters
- Subjects :
- Condensed Matter - Statistical Mechanics
Subjects
Details
- Database :
- arXiv
- Publication Type :
- Report
- Accession number :
- edsarx.0808.3271
- Document Type :
- Working Paper