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Approximate square-root-time relaxation in glass-forming liquids

Authors :
Nielsen, Albena I.
Christensen, Tage
Jakobsen, Bo
Niss, Kristine
Olsen, Niels Boye
Richert, Ranko
Dyre, Jeppe C.
Source :
J. Chem. Phys. 130, 154508 (2009)
Publication Year :
2007

Abstract

We present data for the dielectric relaxation of 43 glass-forming organic liquids, showing that the primary (alpha) relaxation is often close to square-root-time relaxation. The better an inverse power-law description of the high-frequency loss applies, the more accurately is square-root-time relaxation obeyed. These findings suggest that square-root-time relaxation is generic to the alpha process, once a common view, but since long believed to be incorrect. Only liquids with very large dielectric losses deviate from this picture by having consistently narrower loss peaks. As a further challenge to the prevailing opinion, we find that liquids with accurate square-root-time relaxation cover a wide range of fragilities.

Details

Database :
arXiv
Journal :
J. Chem. Phys. 130, 154508 (2009)
Publication Type :
Report
Accession number :
edsarx.0712.2827
Document Type :
Working Paper
Full Text :
https://doi.org/10.1063/1.3098911