Back to Search
Start Over
Approximate square-root-time relaxation in glass-forming liquids
- Source :
- J. Chem. Phys. 130, 154508 (2009)
- Publication Year :
- 2007
-
Abstract
- We present data for the dielectric relaxation of 43 glass-forming organic liquids, showing that the primary (alpha) relaxation is often close to square-root-time relaxation. The better an inverse power-law description of the high-frequency loss applies, the more accurately is square-root-time relaxation obeyed. These findings suggest that square-root-time relaxation is generic to the alpha process, once a common view, but since long believed to be incorrect. Only liquids with very large dielectric losses deviate from this picture by having consistently narrower loss peaks. As a further challenge to the prevailing opinion, we find that liquids with accurate square-root-time relaxation cover a wide range of fragilities.
- Subjects :
- Condensed Matter - Soft Condensed Matter
Subjects
Details
- Database :
- arXiv
- Journal :
- J. Chem. Phys. 130, 154508 (2009)
- Publication Type :
- Report
- Accession number :
- edsarx.0712.2827
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1063/1.3098911