Back to Search
Start Over
Depletion potential in the infinite dilution limit
- Source :
- J. Chem. Phys. 128, 134507 (2008); 140, 179901(E) (2014)
- Publication Year :
- 2007
-
Abstract
- The depletion force and depletion potential between two in principle unequal "big" hard spheres embedded in a multicomponent mixture of "small" hard spheres are computed using the Rational Function Approximation method for the structural properties of hard-sphere mixtures [S. B. Yuste, A. Santos, and M. L\'opez de Haro, J. Chem. Phys. {\bf 108}, 3683 (1998)]. The cases of equal solute particles and of one big particle and a hard planar wall in a background monodisperse hard-sphere fluid are explicitly analyzed. An improvement over the performance of the Percus-Yevick theory and good agreement with available simulation results are found<br />Comment: 10 pages, 5 figures; v2: few minor additions and reduction in the number of figures; v3: Fig. 2 corrected (see http://dx.doi.org/10.1063/1.4874639)
Details
- Database :
- arXiv
- Journal :
- J. Chem. Phys. 128, 134507 (2008); 140, 179901(E) (2014)
- Publication Type :
- Report
- Accession number :
- edsarx.0711.3633
- Document Type :
- Working Paper
- Full Text :
- https://doi.org/10.1063/1.2841172