Solubilised bright blue-emitting iridium complexes for solution processed OLEDs† †Electronic supplementary information (ESI) available: Synthesis CIF of the crystal structures. CCDC 1440897–1440899. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6tc00151c Click here for additional data file. Click here for additional data file

Combining a sterically bulky, electron-deficient cyclometalating C∧N ligands with an electron rich, highly rigidified N∧N ligand gives an iridium complex, that achieves extraordinarily bright blue emission (Φ PL = 90%; λ max = 459 nm in MeCN) for a cationic iridium complex.
Combining a sterically bulky, electron-deficient 2-(2,4-difluorophenyl)-4-(2,4,6-trimethylphenyl)pyridine (dFMesppy) cyclometalating C∧N ligand with an electron rich, highly rigidified 1,1′-(α,α′-o-xylylene)-2,2′-biimidazole (o-xylbiim) N∧N ligand gives an iridium complex, [Ir(dFMesppy)2(o-xylbiim)](PF6), that achieves extraordinarily bright blue emission (Φ PL = 90%; λ max = 459 nm in MeCN) for a cationic iridium complex. This complex is compared with two reference complexes bearing 4,4′-di-tert-butyl-2,2′-bipyridine, and solution-processed organic light emitting diodes (OLEDs) have been fabricated from these materials.