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[BiOBr promoted the photocatalytic degradation of beta-cypermethrin under visible light]

Authors :
Yi-Zhu, Peng
Xiao-Rong, Zhao
Man-Ke, Jia
Wei, Zhou
Ying-Ping, Huang
Source :
Huan jing ke xue= Huanjing kexue. 35(5)
Publication Year :
2014

Abstract

As a visible light photocatalyst, bismuth oxide bromide (BiOBr) was used to catalyze the degradation of beta-cypermethrin (beta-CP). The photocatalytic degradation of beta-CP was studied with gas chromatography. The effects of pH and catalyst dose on the photocatalytic degradation efficiency were discussed. The oxidization and mineralization of beta-CP were detected by chemical oxygen demand (COD) analyzer. The results showed that beta-CP could be effectively degraded under visible light irradiation using BiOBr as the catalyst. At given experimental conditions, the degradation rate of beta-CP reached 94. 68% after 10 h and the COD removal rate reached 67. 99% after 36 h. With the increase of catalyst dose and pH value, the degradation rate was improved. The photocatalytic oxidation species was determined by peroxidase method and terephthalic acid fluorescence method. These results suggested that the photocatalytic degradation process mainly referred to hydroxyl radical ( OH) mechanism.

Details

ISSN :
02503301
Volume :
35
Issue :
5
Database :
OpenAIRE
Journal :
Huan jing ke xue= Huanjing kexue
Accession number :
edsair.pmid..........c010ec2b70425befed8e7ebb86e13a1e