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Naked eye sensing of toxic metal ions in aqueous medium using thiophene-based ligands and its application in living cells
- Source :
- Journal of molecular recognition : JMR. 27(3)
- Publication Year :
- 2013
-
Abstract
- Thiophene-based diimine (R1) and monoimine (R2) were synthesized in a single step, and their cation binding affinity was tested using colorimetric and UV-vis spectral studies. R1 selectively shows a colorimetric turn-on response for Pb(2+), Hg(2+) ions and colorimetric turn-off with Sn(2+) ions, and R2 shows visual response for Cu(2+) and Hg(2+) over other examined metal ions in aqueous medium. R1 forms 1:1 complex with Pb(2+), Hg(2+), and Sn(2+) and exhibits fluorescence quenching, whereas R2 shows 2:1 complex with Hg(2+), Cu(2+) and shows fluorescence enhancement. The structural and electronic properties of the sensors and their metal complexes were also investigated using Density Functional Theory calculations. R2 was also successfully demonstrated as a fluorescent probe for detecting Cu(2+) ions in living cells.
Details
- ISSN :
- 10991352
- Volume :
- 27
- Issue :
- 3
- Database :
- OpenAIRE
- Journal :
- Journal of molecular recognition : JMR
- Accession number :
- edsair.pmid..........af658dc35d7d8757de35658dbc5f4411