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Correlating Mechanical Sensitivity with Spin Transition in the Explosive Spin Crossover Complex [Fe(Htrz)

Authors :
Thuy-Ai D, Nguyen
Jacqueline M, Veauthier
Gary F, Angles-Tamayo
David E, Chavez
Ekaterina, Lapsheva
Thomas W, Myers
Tammie R, Nelson
Eric J, Schelter
Source :
Journal of the American Chemical Society. 142(10)
Publication Year :
2020

Abstract

Spin crossover complexes are known to undergo bond length, volume, and enthalpy changes during spin transition. In an explosive spin crossover complex, these changes could affect the mechanical and initiation sensitivity of the explosive and lead to the development of a new class of sensitivity switchable materials. To explore this relationship, the well-known spin crossover compound [Fe(Htrz)

Details

ISSN :
15205126
Volume :
142
Issue :
10
Database :
OpenAIRE
Journal :
Journal of the American Chemical Society
Accession number :
edsair.pmid..........a0af3822b6fbb12acb87d90871e8fa89