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Correlating Mechanical Sensitivity with Spin Transition in the Explosive Spin Crossover Complex [Fe(Htrz)
- Source :
- Journal of the American Chemical Society. 142(10)
- Publication Year :
- 2020
-
Abstract
- Spin crossover complexes are known to undergo bond length, volume, and enthalpy changes during spin transition. In an explosive spin crossover complex, these changes could affect the mechanical and initiation sensitivity of the explosive and lead to the development of a new class of sensitivity switchable materials. To explore this relationship, the well-known spin crossover compound [Fe(Htrz)
Details
- ISSN :
- 15205126
- Volume :
- 142
- Issue :
- 10
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.pmid..........a0af3822b6fbb12acb87d90871e8fa89