The construction of a two-dimensional organic-inorganic hybrid double perovskite ferroelastic with a high

Two-dimensional (2D) hybrid double perovskites have attracted extensive research interest for their fascinating physical properties, such as ferroelectricity, X-ray detection, light response and so on. In addition, ferroelastics, as an important branch of ferroic materials, exhibits wide prospects in mechanical switches, shape memory and templating electronic nanostructures. Here, we designed a 2D phase-transition double perovskite ferroelastic through a structurally progressive strategy. This evolution is core to our construction process from 0D to 1D and AgBi-based 2D. In this way, we successfully synthesized 2D lead-free ferroelastic (DPA)