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Stable and Active Oxidation Catalysis by Cooperative Lattice Oxygen Redox on SmMn

Authors :
Yongping, Zheng
Sampreetha, Thampy
Nickolas, Ashburn
Sean, Dillon
Luhua, Wang
Yasser, Jangjou
Kui, Tan
Fantai, Kong
Yifan, Nie
Moon J, Kim
William S, Epling
Yves J, Chabal
Julia W P, Hsu
Kyeongjae, Cho
Source :
Journal of the American Chemical Society. 141(27)
Publication Year :
2019

Abstract

The correlation between lattice oxygen (O) binding energy and O oxidation activity imposes a fundamental limit in developing oxide catalysts, simultaneously meeting the stringent thermal stability and catalytic activity standards for complete oxidation reactions under harsh conditions. Typically, strong O binding indicates a stable surface structure, but low O oxidation activity, and

Details

ISSN :
15205126
Volume :
141
Issue :
27
Database :
OpenAIRE
Journal :
Journal of the American Chemical Society
Accession number :
edsair.pmid..........8105993a2d83ddf9a9c5c4af4724d0aa