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H-Bonding and intramolecular catalysis of proton exchange affect the CEST properties of Eu

Authors :
Simona, Baroni
Irene Maria, Carnovale
Carla, Carrera
Mariangela, Boccalon
Nicol, Guidolin
Nicola, Demitri
Luciano, Lattuada
Fabio, Tedoldi
Zsolt, Baranyai
Silvio, Aime
Source :
Chemical communications (Cambridge, England). 57(26)
Publication Year :
2021

Abstract

Eu(HP-DO3A) is present in solution as a mixture of two diastereoisomers whose alcoholic groups are the source of the mobile protons for the CEST effect. The exchange is base catalyzed. Two novel Eu

Details

ISSN :
1364548X
Volume :
57
Issue :
26
Database :
OpenAIRE
Journal :
Chemical communications (Cambridge, England)
Accession number :
edsair.pmid..........7e473af9c7ec3210812b0d675d6f14e9