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Sensing the framework state and guest molecules in MIL-53(Al) via the electron paramagnetic resonance spectrum of V

Authors :
Irena, Nevjestić
Hannes, Depauw
Peter, Gast
Pieter, Tack
Davy, Deduytsche
Karen, Leus
Melissa, Van Landeghem
Etienne, Goovaerts
Laszlo, Vincze
Christophe, Detavernier
Pascal, Van Der Voort
Freddy, Callens
Henk, Vrielinck
Source :
Physical chemistry chemical physics : PCCP. 19(36)
Publication Year :
2017

Abstract

X-ray diffraction (XRD) and electron paramagnetic resonance spectroscopy (EPR) were combined to study the structural transformations induced by temperature, pressure and air humidity of the "breathing" metal-organic framework (MOF) MIL-53(Al), doped with paramagnetic V

Details

ISSN :
14639084
Volume :
19
Issue :
36
Database :
OpenAIRE
Journal :
Physical chemistry chemical physics : PCCP
Accession number :
edsair.pmid..........6b7b97950e959f20bee9ce50bd1e83c1